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Nanosecond laser flash-photolysis technique was used to study bimolecular and geminate molecular oxygen (O 2 ) rebinding to α and β subunits within oxygenated human adult hemoglobin in solutions and porous wet sol–gel matrices. Plasticity associated with the tertiary structure within R-state hemoglobin is explored through measurements that focus on the functional properties of hemoglobin under...
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