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For taking full advantages of electrochemical synthesis and high selectivity of peroxydisulfate for oxidation of alcohol to aldehyde, the electrocatalyst Ti-TiNxO2−x-Pt and electrolysis-separation device were constructed. The synergetic effect between the Ti-TiNxO2−x-Pt with the suitable catalytic performance for electro-oxidation of HSO4− to peroxydisulfate and the electrolysis-separation device...
A new catalytic reaction for the single-step synthesis of o-vinylphenol from phenol and acetaldehyde in the gas phase is investigated in this work. A search for an efficient catalyst was made. The best results were obtained with a modified Cr2O3 catalyst supported on γ-Al2O3. The effect of content of Cr2O3 and potassium as a modifying additive was studied. It was shown that the catalyst containing...
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