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Supported gold nanoparticles of sizes 5–8nm have been found as highly efficient catalyst for the oxidation of 1,4 dioxane, a saturated ether, using elemental oxygen at low temperature. GC–MS analysis of the reaction mixture showed >85% conversion of 1,4 dioxane with a TON of 1120h−1 to 1,4 dioxan-2-ol with 90% selectivity. 1,4 Dioxan-2-one was obtained as the major byproduct along with traces of...
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