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A dynamic model was developed to describe the oxidation of Cu in a large-scale Cu/CuO chemical looping process performed in adiabatic fixed-bed reactors at high pressure. An ideal plug flow pattern without axial dispersion or radial gradients and with negligible intra-particle concentrations and temperature gradients on the scale of millimeters were assumed. Cu oxidation is favoured at high pressure...
This work presents a comprehensive conceptual design of a Ni-based chemical looping combustion process (CLC) carried out in fixed bed reactors. The process is intended to exploit the well-known advantages of the Ni/NiO redox system for CLC applications in terms of high reactivity, O2 carrying capacity and chemical and thermal stability. Solutions to the problem of heat management in fixed bed reactors...
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