In this paper, a ceramic perovskite anode for solid oxide fuel cells (SOFCs) is prepared by infiltrating La and Fe co-doped strontium titanium, La0.3Sr0.7Ti0.3Fe0.7O3-δ (LSTF0.7) into porous backbone of scandia-stabilized zirconia (ScSZ) and tested in pure H2 at 700–850°C. LSTF0.7 crystal exhibits high reduction stability and good compatibility with ScSZ electrolyte under reducing atmosphere. In order to improve the electrocatalytic activity, 15wt% of CeO2 and 7wt% of Ni are infiltrated into the backbone pores respectively, thus forming LSTF0.7-CeO2 and Ni-CeO2-LSTF0.7 composite anodes. The cell with LSTF0.7 single anode shows a relatively lower maximal power density (MPD) of 401mWcm−2 in H2 at 800°C. While the maximal power densities of the cells with LSTF0.7-CeO2 and Ni-CeO2-LSTF0.7 composite anodes are 612mWcm−2 and 698mWcm−2 operated at the same conditions, respectively. The three anode polarization resistances (Rp,a) distinguished from the corresponding full cells are 0.176, 0.086 and 0.076Ωcm2 at 800°C, respectively. The values of the activation energy (Ea) towards H2 oxidation for the three anodes can be calculated to be 52.2, 46.0, 43.9kJmol−1 based on their respective Rp,a. Therefore, the LSTF0.7-based anodes are considered to be promising alternatives for solid oxide fuel cell applications.