The static polarization of HD samples has been achieved using “brute force”, for HD samples purified by double distillation. Proton polarization in excess of 60% and deuteron vector polarization higher than 14% have been reached. It has been demonstrated that the ageing technique allows to get relaxation times at 1.5K and 1T larger than a week. It is advocated that the conventional dynamic polarization of HD should be feasible for the proton and the deuteron contained in the HD molecule. This would create the possibility of polarizing DT molecules, increasing their reactivity when used as fuel in HIIF processes.