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Extremely large crystal grains are obtained by bromine doping in electrodeposited Cu 2 O on indium tin oxide (ITO) substrate through an acetate bath. The grains are as large as 10,000μm 2 in area, or ~100μm in linear dimension, while the film is only 1–5μm thick. The enhanced grain size is explained by the effect of over-potential for the Cu 2+ /Cu + redox couple on...
The effect of varying the boron and aluminium content of the starting electrolyte for extrinsically doped ZnO films grown on SnO2:F substrates by electrochemical deposition was investigated. The ZnO:B film surface was characterized by grains with mainly hexagonal faces exposed while the exposed faces of the ZnO:Al grains were rectangular. Whereas a B3+/Zn2+ ratio of up to 10at.% in the electrolyte...
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