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The Raman scattering analysis of S-rich CuIn(S,Se) 2 layers produced by electrodeposition of CuInSe 2 precursors and annealing under sulphurising conditions shows the strong dependence of their crystalline quality on the annealing parameters. Worsening of the crystalline quality is reflected by the presence of an increasing contribution at the higher frequency side of the main Raman...
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