The synthesis, characterisation and the study of the reactivity of the novel and bifunctional ferrocenyl Schiff bases [Fe{(η 5 -C 5 H 4 )-C(Me) N-N C(H)(C 6 H 3 -2,6-R 2 )} 2 ] (with R=Cl or H) with palladium(II) salts under different experimental conditions are reported. The treatment of Na 2 [PdCl 4 ], Na(CH 3 COO).3H 2 O and the corresponding ligand [Fe{(η 5 -C 5 H 4 )-C(Me) N-N C(H)(C 6 H 3 -2,6-R 2 )} 2 ] (with R=Cl or H) (in a 2:2:1 molar ratio) in methanol for 6 days followed by the addition of triphenylphosphine (PPh 3 ), and a SiO 2 column chromatography, allowed the isolation of the two isomers (meso- and d,l- forms) of the heterotrimetallic complexes of general formula [Pd 2 {Fe[(η 5 -C 5 H 3 )-C(Me) N-N C(H)(C 6 H 5 -2,6-R 2 )] 2 }Cl 2 (PPh 3 ) 2 ], (with R=Cl or H).