Micro-copper flakes were coated with nano-TiO 2 in an ethanol-based colloid sol by chemical deposition, in order to improve their oxidation resistance. The as-prepared composites were characterized by field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), Raman spectroscopy, X-ray photoelectron spectroscopy (XPS) and X-ray diffraction (XRD). Results showed that TiO 2 nanocrystals (predominantly anatase) of approximate 10nm in size were successfully deposited on the surface of Cu flakes, forming a granular coating. The growth of titania on the copper flakes seems to be implemented by anchoring TiO 2 through Ti-O-Cu bonds. The thermal stability of the composites was tested by thermogravimetric analysis (TGA) in an air atmosphere. The results showed that TiO 2 -coated copper flakes acquired better oxidation resistance compared to the pure copper flakes. Oxidation in air of pure copper flakes began at 190°C, whereas the composites did not oxidize until 360°C.