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Introduction of the citric acid in the borate system generates a new phase, Ca[B(C 6 H 6 O 7 ) 2 ](H 2 O) 4 ⋅HCl, which is transparent from 195nm to near infrared region. Single crystals of Ca[B(C 6 H 6 O 7 ) 2 ](H 2 O) 4 ⋅HCl with dimensions up to 7×5×2mm 3 were successfully grown by slow evaporation...
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