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When dpktch was allowed to react with HgCl 2 in acetonitrile under reflux, [HgCl 2 (κ 2 -N,N′-dpktch)] was isolated in good yield. Infrared spectra disclosed the absence of HgO coordination and 1 H NMR studies in d 6 -dmso revealed that [HgCl 2 (κ 2 -N,N′-dpktch)] is sensitive to its environment and that its amide proton is exchangeable. Electronic...
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