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Reactions of unsaturated hydrocarbons with fluoroformyl cation (CFO + ) and of ketene and diketene with CFO + and CF 3+ have been studied in a Flowing Afterglow-Selected Ion Flow Tube (FA-SIFT) in helium at room temperature. Net F + transfer from CFO + to the neutral reactants, which is observed in the majority of cases studied, can be explained in terms...
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