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The interaction of lithium ions with the nucleic acid bases which make up the A:T base pair, adenine and thymine, as well as the hydration of the complex by one water molecule has been studied in the gas phase. An IRMPD spectrum is reported for [A–T–Li + ]–H 2 O (A=adenine, T=thymine) over the N–H stretching region, 3200–3800cm −1 . Calculations were performed using the B3LYP...
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