Cracks that induce deformation in ablators reinforced with Kynol-based carbon fibers during pyrolysis reactions are assessed using experimental observations and theoretical estimation of tensile stress. Tensile stress in the transverse direction is produced by mismatch strain between the fiber and matrix during pyrolysis reactions and subsequently generates cracks. Observations and theoretical estimations of tensile stress using a model showed that cracking triggers buckling of fiber bundles, which consequently expands the ablator in the thickness direction. When large pores exist in the matrix, cracking relaxes the mismatch strain when tensile stress is low, thereby suppressing the buckling.