Asymmetrical induction in the synthesis of bicyclic pyrazolines with a ferrocenyl substituent has been studied. A relatively high diastereomeric selectivity in the 'chiral-center-by-a-chiral-center' induction of the 1,2-type has been observed. Molecular geometry of a cis-diastereomer of 1-acetyl-9-ferrocenyl-4-ferrocenylmethylene-1,2-diazabicyclo[4.3.0]non-2-ene has been established. Bicyclic 2-pyrazolines having conjugated ferrocenylmethylene fragments interact with azodicarboxylic acid N-phenylimide to form diene and monoene adducts.