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A new nickel complex [Ni(1,3-bis(diphenylphosphino)propane)((2-mercaptopyridinate)-κN,S)]BF4 was synthesized and characterized by NMR spectroscopy, an X-ray crystallographic study, elemental analysis and electrospray ionization mass spectroscopy. The complex was synthesized under ambient conditions and was air-stable. Catalytic behavior for electrochemical production of hydrogen was investigated by...
Herein, we present the preparation and characterization of two nickel dithiolene complexes, namely [Ni(C3{S2C2Ph2}2)] (1) and [Ni(C3{p-OMe-C6H4}2)] (2). X-ray diffraction data for 2 collected on single crystals reveal that the complex is a neutral mononuclear entity with symmetric square planar geometry around the metal center. Electrochemical, photophysical, and theoretical studies have been employed...
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