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Six complexes of various Mn(II) salts: MnBr2·4H2O (1), Mn(NO3)2·4H2O (2), MnCl2·4H2O (3) with 2-(1-methyl-2-(pyridin-2-ylmethylene)hydrazinyl)benzo[d]oxazole LA (complexes 1A–3A) and 2-(2-((1H-imidazol-4-yl)methylene)-1-methylhydrazinyl)benzo[d]oxazole HLB (complexes 1B–3B) have been synthesized. All complexes were obtained in 1:1 stoichiometry. Their structures have been established through analytical...
The degradation of hexachloroethane using chloridobis(dimethylglyoximato)pyridinecobalt(III), chloridobis(methylphenylglyoximato)pyridinecobalt(III) and chloridobis(diphenylglyoximato)pyridinecobalt(III) is described. To achieve the degradation, the cobalt complexes were reduced to the Co(I) oxidation state by electrochemical means. The chemical catalysis was studied using cyclic voltammetry by monitoring...
Reaction of Ph2P(Se)CSNHPh with Cp2Fe2(CO)4 in refluxing toluene affords complexes CpFe(CO)(k2P,S-Ph2PC(S)NPh) (1) and CpFe(CO)2(kP-P(Se)Ph2) (2). Further, reactions of 2 with 1 equiv of PPh2R in the presence of Me3NO generate complexes CpFe(CO)(kSe-SeP(Se)Ph2)(L) (3, L = PPh3; 4, L = PPh2Py). Unlike 2, reactions of CpFe(CO)2(kP-P(S)Ph2) with PPh2R under the same conditions give the corresponding...
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