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Two imidazolium-tagged biphenyldicarboxylates were synthesized and incorporated into the UiO-67 framework. Post synthetic exchange did not prove a useful route to these materials. Alternatively, mixed-linker synthesis of the solid afforded materials loaded with 6–7% imidazolium linker, corresponding to fewer than one active site per cage. Powder X-ray diffraction patterns for the doped metal–organic...
The synthesis, characterization, and catalytic activity of bis(2-pyridylmethyl)amine (BPMA) copper complexes incorporating olefinic pendent arms are reported. Four copper(I) and four copper(II) complexes were synthesized employing four different counterions [chloride (Cl−), perchlorate (ClO4−), trifluoromethanesulfonate (CF3SO3−), and tetraphenylborate (BPh4−)]. The counterions used ranged from coordinating...
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