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Three new hybrid nitrate materials based on transition metals and templated by piperazine, (C4H12N2)3[MII(H2O)6](NO3)8 with MII: Mn (1), Cu (2) and Co (3) have been investigated and crystallographically characterized. The single crystal X-ray diffraction study shows that the three complexes crystallize in the triclinic system, space group P1¯. Within the adopted supramolecular structures, isolated...
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