The Infona portal uses cookies, i.e. strings of text saved by a browser on the user's device. The portal can access those files and use them to remember the user's data, such as their chosen settings (screen view, interface language, etc.), or their login data. By using the Infona portal the user accepts automatic saving and using this information for portal operation purposes. More information on the subject can be found in the Privacy Policy and Terms of Service. By closing this window the user confirms that they have read the information on cookie usage, and they accept the privacy policy and the way cookies are used by the portal. You can change the cookie settings in your browser.
A kinetic analysis of the hydroboration of iso-quinoline with pinacol borane (HBpin) and catalysed by a β-diketiminato magnesium n-butyl pre-catalyst has provided evidence that the reaction proceeds via rate determining Mg–N/H–B metathesis of a dearomatised iso-quinolide anion. The reaction rate is suppressed by increasing [iso-quinoline] leading to the suggestion that catalytic turnover is also dependent...
BDI∗MgnBu(THF) and rac-LA to produce heterotactic PLA have been shown to increase from Pr=0.5–0.65 from DCM to neat THF. The increase in concentration of THF from MTHF=0 in toluene to neat THF is shown to occur by THF dissociation as deduced by 1H NMR studies. In related systems where X=nBu and OtBu and with ligands L=THF, py and DMAP similar processes occur by which external exchange of L occurs...
Set the date range to filter the displayed results. You can set a starting date, ending date or both. You can enter the dates manually or choose them from the calendar.