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A new thermodynamic model based on the free volume theory and the lattice model was proposed for solid solutions. A significant advantage of the model lies in its ability to predict the thermodynamic properties of solid solutions using only the binary infinite dilute activity coefficients and the predicted values are in good agreement with their experimental data. This shows that the model with a...
We have summarized experimental data on the phase diagram of the system Ag 2 S–Ag 2 Se. Standard thermodynamic functions of four solid solutions in this system have been calculated using the model of regular and subregular solutions: a restricted fcc solid solution γ-Ag 2 S-Ag 2 S 1−x Se x (x<0.3, 867<T<1110K) and complete bcc solid solution...
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