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The thermodynamic modeling and optimization of the Ge–Sb and Ge–Sb–Sn systems were critically carried out by means of the CALPHAD (CALculation of PHAse Diagram) technique. The solution phases, liquid, diamond, bct and rhombohedral, were described by the substitutional solution model. The compound SbSn was treated as the formulae (Ge,Sb,Sn) 1 (Ge,Sb,Sn) 1 in the Ge–Sb–Sn system. A self-consistent...
The thermodynamic properties of the ternary Au–Cu–Sn system were determined with the electromotive force (EMF) method using a liquid electrolyte. Three different cross-sections with constant Au:Cu ratios of 3:1, 1:1, and 1:3 were applied to measure the thermodynamic properties of the ternary system in the temperature range between the liquidus temperature of the alloys and 1023K. The partial free...
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