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New data on the dehydration and rehydration processes of calcium, manganese and copper dichlorides are presented that reveal surprising, in a certain sense, behaviour difficult to be explained for the last two chlorides in terms of the usual conception of thermodynamic equilibrium. A substantial role of a super disperse phase at studying the equilibrium of the thermal decomposition of a hydrate is...
Mixtures with dimethyl or trimethylpyridines and alkane, aromatic compound or 1-alkanol have been examined using different theories: DISQUAC, Flory, the concentration–concentration structure factor, S CC (0), or the Kirkwood–Buff formalism. DISQUAC represents fairly well the available experimental data, and improves theoretical calculations from Dortmund UNIFAC. Two important effects have...
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