Neel (T N ) and Weiss (Θ) temperatures of the alkali-electro-sodalites (AES) loaded with Na or K were investigated as a function of hydrostatic pressure up to 2GPa with a low-frequency ESR technique. T N depends weakly on the pressure, but Θ decreases more sensitively with the pressure. The transfer energies t 1 and t 2 via the two-kinds of coupling windows, hexagons and squares, respectively, are derived with the tight-binding and the two-sublattice molecular field approximations. Assuming that the transfer energies are suppressed by the pressure exponentially, the observed pressure dependence of T N and Θ can be reproduced very well and suggested that the electronic states in Na-ES can be scaled to that in K-ES with a chemical pressure of ~4GPa.