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Enantioselective reduction of a series of substituted aryl trichloromethyl ketones with the CBS-catecholborane reagent afforded homochiral aryl trichloromethyl carbinols which have been elaborated to give homochiral α-arylglycines in high e.e.
The Dyson Perrins Laboratory, University of Oxford, South Parks Road, Oxford OX1 3QY, UK
Laboratoire de Chimie Thérapeutique associé au CNRS, Faculté des Sciences Pharmaceutiques et Biologiques, Université René Descartes, Paris V, 4 Avenue de l'Observatoire, 75270 Paris cedex, France
Laboratoire SEESIB-CNRS, Département de Chimie, Université Blaise Pascal - Clermont-Ferrand II, 24 Avenue des Landais, 63177 Aubière cedex, France
Laboratoire de Chimie Thérapeutique associé au CNRS, Faculté des Sciences Pharmaceutiques et Biologiques, Université René Descartes, Paris V, 4 Avenue de l'Observatoire, 75270 Paris cedex, France