Over 400 X∼←A∼ transitions of SCCl 2 have been measured by stimulated emission pumping from 209 to 240THz above the X∼ state zero point. The A∼ state provides access to over 100 previously unassigned X∼ state vibrational levels. The vibrational manifold of SCCl 2 now has been mapped to maximum quanta in all six modes of (15, 4, 5, 18, 2, 2), providing a global view of vibrational dynamics. We report anharmonic constants that fit all currently available assigned vibrational energy levels. The onset of free energy flow has not been reached at E/h=240THz for states sampled here, in accordance with B∼ state SEP data and a theoretical analysis.