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Based on the trigonal symmetry of the title triazine 1 and the Br 3 supramolecular synthon, a hexagonal host system has been designed and shown to include hexachlorobenzene, 2,4,6-collidine, 1-methylnaphthalene and mesitylene guests in its porous structure. In the 1.hexachlorobenzene (2:1) inclusion clathrate 2, the guest molecule is ordered and bonded to the host through Cl...O interactions...
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