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Electronic structures of Co x Pd 100-x alloy films have been investigated using photoemission spectroscopy. The extracted Co 3d partial spectral weight (PSW) distribution exhibits interesting features at x = 25% reflecting large Co 3d/Pd 4d hybridization, and the Pd 4d PSW becomes broader as x increases. Calculated partial densities of states of Co x Pd 100-x compounds are found to be qualitatively consistent with experiment.