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A surface-segregated thin layer of poly(dimethylsiloxane)-block-poly(methylmethacrylate) (PDMS-b-PMMA) formed by self-organization during spin-coating was utilized as an interfacial buffer layer in organic photovoltaic cells. X-ray photoelectron spectroscopy revealed that PDMS-b-PMMA mixed into the coating solution spontaneously accumulated at the surface of the active layer due to the low surface...
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