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Air-stable and high-mobility polymer-based organic thin-film transistors are developed by employing low-surface-energy self-assembled monolayers and prolonged post-annealing. Carrier mobility in spin-coated thin films of a high-ionic-potential polymer semiconductor poly(2,5-bis(2-thienyl)-3,6-dihexadecyltheino[3,2-b]thiophene) reaches (0.08–0.17cm 2 /Vs with decyltriethoxysilane monolayers...
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