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The ethyl radical was observed in a low-pressure premixed gasoline/oxygen/argon flame by using tunable vacuum ultraviolet photoionization mass spectrometry. The ionization energy (IE) of the ethyl radical was derived to be (8.24 ± 0.02) eV from the photoionization efficiency curve. In addition, a high-level ab initio Gaussian-3 (G3) method was used to calculate the energies of the radical and its...
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