Tribological property of copper-based friction materials with exogenous copper powder third body was investigated. Friction tests were conducted under the friction speeds (100–1500rpm) and pressures (0.25MPa, 0.38MPa and 0.51MPa) by a pin-on-disc tribometer. The results indicate that the friction coefficient can be average increased by 0.03 by the presence of exogenous copper powder on the friction surface compared with the non-exogenous copper-based friction materials. There are two main reasons: exogenous copper powder third body increases the actual contact area; exogenous copper powder particles are compacted forming dense third body. But, for non-exogenous copper-based friction materials, less particles and the piece shape nature third bodies are compacted, which consume less friction force leading to lower friction coefficient.