The surface chemical properties and morphology changes that occurred on carbon nanotubes after modification by oxygen dielectric barrier discharge (DBD) at atmospheric pressure were investigated by dispersion test, XPS, FTIR, Raman, SEM and nitrogen adsorption. The effects of plasma treatment parameter, such as discharge power and treatment time, have been conducted. At the power of 15W following 40min exposure to the discharge, the surface atomic oxygen percentage could increase from 1.90% to 7.47%. Meanwhile, the surface area increased from 125m 2 /g to 156m 2 /g and the total volume from 0.309cm 3 /g to 0.358cm 3 /g. The possible mechanism is drawn for the modification process. Firstly, the plasma would attack on the defect site, transformed the sp 2 -hybridized carbons in nanotubes framework into sp 3 -hybridization and introduce the oxygen-containing functional groups including OH, COOH groups within 10min. Furthermore, the hydroxyl groups could be further oxidized to form carboxyl groups. Moreover, the COOH groups were further oxidized to CO 2 and H 2 O under excessive exposure time causing the decrease of the amount of oxygen atom. This investigation may be a simple and nonpolluting method for the modification of MWCNTs.