1′-(Diphenylphosphino)-1-(N-butylcarbamoyl)ferrocene (P1) and the analogous higher amides P2–4 related to the first-generation PAMAM dendrimers bearing up to four 1′-(diphenylphosphino)ferrocen-1-yl terminal groups were synthesized by amidation of the respective (poly)amines with 1′-(diphenylphosphino)ferrocenecarboxylic acid (Hdpf). Testing of amides P1–4 as ligands for palladium-catalyzed Suzuki and Heck coupling reactions has shown that these amidophosphines preserve the activity of the single phosphinoferrocenyl unit, giving rise to active catalysts in both C–C forming reactions. Even for such relatively small systems, a positive influence of the dendritic assembly was notable as the compounds bearing a higher number of the phosphinoferrocenyl termini afforded faster reacting catalytic systems at the same palladium loading and P-to-Pd ratio.