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Hg 0.84 Zn 0.16 Te crystals were grown vertically by back-melting a series of precast segments followed by directional solidification. The predetermined composition profiles of these segments simulate the distribution of a diffusion boundary layer in the melt ahead of the solid-melt interface during the directional solidification experiment. Composition analysis of the grown crystals confirm that steady-state growth were achieved from the beginning of the growth process.