All-organic PDLC (polymer-dispersed liquid crystal) light-valves using all-polymer conductive substrates containing thin films of polypyrrole doped with anthraquinone-2-sulfonate (AQSA − ) as the driving electrodes were fabricated in this study. The all-polymer conductive substrates were prepared under ambient conditions by in situ depositing polypyrrole thin films on blank flexible poly(ethylene terephthalate), or PET, substrates from aqueous media in which oxidative polymerization of pyrrole was taking place. The obtained flexible all-polymer conductive substrates were semi-transparent with cohesive coatings of AQSA − -doped polypyrrole thin films (thickness ∼55nm). The all-polymer flexible conductive substrates had sheet resistivity ∼40kΩ□ −1 and T% transparency against air ∼78% at 600nm. The light-valves fabricated using the above all-polymer conductive substrates showed ∼50% transparency against air at 600nm when 4Vμm −1 electric field was applied.