The measurement of different reactions of pd annihilation at rest in a gaseous target has been performed using the OBELIX spectrometer at LEAR (CERN). A strong deviation from the OZI-rule prediction was found from the measurement of the ratio R = φπωπ in two regions of proton momenta, P < 200 MeV/c and P > 400 MeV/c:R(φπ - ωπ - ) = (133 ± 26) 10 - 3 and (113 ± 30) 10 - 3 , respectively. These values are about 30 times greater than the theoretical prediction. For the first time the excitation of the Δ-resonance was observed among the final-state products of pd annihilation. The existence of a broad enhancement in the 4π invariant mass at m 1480 MeV, seen in previous experiments, was confirmed. A 100 MeV downward shift of the bump position, when the proton momentum increased up to P > 400 MeV/c, was also observed, while the positions of ω, ρ and f 2 (1270) did not change with the proton momentum. The following branching ratios were measured: BR(pd → π - φp) = (6.62 ± 0.49) 10 - 4 , for P < 200 MeV/c; BR(pd → π - φp) = (0.95 ± 0.22) 10 - 4 , for P > 400 MeV/c; BR(pd → π - ωp) = (49.7 ± 8.9) 10 - 4 , for P < 200 MeV/c; BR(pd → π - ωp) = (8.38 ± 1.09) 10 - 4 , for P > 400 MeV/c; BR(pd → 2π - π + p) = (150 ± 6) 10 - 4 , for P < 200 MeV/c; BR(pd → 2π - π + p) = (16.6 ± 0.9) 10 - 4 , for P > 400 MeV/c; BR(pd → 3π - 2π + p) = (326 ± 12) 10 - 4 , for P < 200 MeV/c; BR(pd → 3π - 2π + p) = (44 ± 7) 10 - 4 , for P > 400 MeV/c; BR(pd → ΛK + π - ) = (0.96 ± 0.19) 10 - 4 , for P > 400 MeV/c; BR(pd → ΛK + π - π 0 ) = (3.5 ± 0.8) 10 - 4 , for P > 400 MeV/c; BR(pp → 2π - 2π + ) = (540 ± 20) 10 - 4 ; BR(pp → 3 3π - 3π + ) = (251 ± 21) 10 - 4 .