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New ion conductive polymer complexes were formed by dissolving various polycation salts into room temperature molten salts containing aluminium chloride. The viscoelastic films were fabricated from the molten salts added at least 10 mol % of the polypyridinium salts. The ionic conductivities of the polymer complexes were 10-100 times higher than poly(ethyleneoxide)-based polymers at room temperature and were affected by their composition.