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Having previously demonstrated that the mineral assemblage of claystone can impose its pCO2 under saturated conditions, we here study the effect of rock desaturation, i.e. the evaporation of pore water, on the partial pressure of CO2 (pCO2) in Callovian–Oxfordian argillite from the Paris Basin (France). In this new study, which combines experiments at room temperature and geochemical modelling, we...
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