The lifetime of ortho-positronium in solid naphthalene shortens with the rise of pressure as a result of diminishing the free spaces in which it is trapped. At the pressure ~100 MPa the size of these spaces is too small to accommodate the Ps atom (no energy level in the well), and the intensity of ortho-Ps component, initially weakly dependent on pressure, abruptly drops to zero. The narrow range in which ortho-Ps disappears indicates uniformity of Ps-accommodating voids. The nonmonotonous dependence of free positron lifetime is discussed in the framework of the blob model.