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Pentacene thin film on CH3NH3PbI3 was studied by in-situ X-ray photoelectron spectroscopy and ultraviolet photoelectron spectroscopy to determine their interfacial energy level alignment. A 0.2eV downward band bending together with a 0.1eV interfacial dipole was found at the pentacene side, whereas there was no band bending found at the CH3NH3PbI3 side. The offset between CH3NH3PbI3 Valance Band Maximum...
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