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The role of palladium precursors (e.g. chloride - PdCl 2 ; acetylacetonate - Pd(acac) 2 ; nitrate - Pd(NO 3 ) 2 ) in the catalytic properties of Pd/Al 2 O 3 and Pd/CeO 2 /Al 2 O 3 catalysts toward CO oxidation was herein investigated. The characterization techniques used for mapping the Pd sites were H 2 and CO chemisorption,...
The phenomena of induction period of methanol formation, observed in CO H 2 reaction over Pd/CeO 2 catalysts under SMSI state, was investigated in depth. The magnitude of the induction period was dependent on the extent of SMSI, and higher temperature H 2 reduction lengthened it accompanied with the increase of the number of active sites for methane formation. On the contrary,...
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