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The hydrogenolysis of CCl 2 F 2 over 1wt.% palladium, platinum, rhodium, ruthenium, iridium, and rhenium on activated carbon has been studied in a micro-flow reactor, in a temperature range of 450-540K, H 2 /CCl 2 F 2 feed ratios between 1.5 and 20, a pressure up to 0.4MPa, and a WHSV between 0.5 and 2g/(gh). The main products of the reaction for all investigated...
A process-development study is presented aiming at the conversion of CCl 2 F 2 into CH 2 F 2 . The CCl 2 F 2 is an undesired compound because of its negative impact on the environment. Palladium on activated carbon is the most appropriate catalyst for this selective hydrogenolysis. During reaction, palladium is present as the carbide (PdC 0....
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