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The catalytic combustion process of air-mixtures containing volatile organic compounds (VOCs) associated with an ionization/ozonization reactor (IOCC technique, ionization-ozonization-catalytic-combustion) has been utilized for the abatement of two very toxic industrial VOCs: acrylonitrile (ACN) and vinyl chloride (VCM). The pre-catalytic effects (electric discharge plus the action of ozone), the...
Alkali metal-promoted MgO catalysts such as Li/MgO, Na/MgO, K/MgO, and Cs/MgO were studied for the acrylonitrile synthesis from methanol and acetonitrile in the range 300-500 o C. The doping of alkali metal with larger cationic radius than that of Mg 2+ increased the basic strength of MgO and facilitated the formation of acetonitrile carbanion, a reaction intermediate for acrylonitrile...
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