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The paper focusses on the identification of molecular structure of carbon species in 15wt.% Co/Al2O3 supported catalyst exposed to different conditions of Fischer–Tropsch synthesis in a continuously stirred tank reactor (CSTR). Characterization of wax-extracted spent catalyst by a combination of techniques showed significant carbon deposition under the conditions where the catalyst exhibited a noticeable...
A detailed kinetic model of the Fischer–Tropsch synthesis (FTS) product distribution based on the CO-insertion mechanism has been derived. The model was developed using the Langmuir–Hinshelwood–Hougen–Watson approach. The intrinsic kinetic parameters were estimated using a set of data obtained in a stirred tank slurry reactor with a rhenium promoted cobalt catalyst over a range of operating conditions...
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