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The aqueous noble metal catalysed alcohol oxidation is a reaction which can profitably be applied in fine-chemistry and for carbohydrate conversion. In this paper engineering aspects of this reaction are treated, i.e. the reaction kinetics, oxygen mass transfer restrictions, catalyst deactivation and reactivation, and implications for reactor design and operation.First a reaction mechanism is proposed,...
The use of membrane reactors in industrial processes leads to high efficiencies because the reaction equilibrium can be shifted towards high conversion and product formation. In addition, the combination of reaction and separation in a single unit operation leads to process simplification and probably hardware cost reduction. A key design factor for membrane reactors is the ratio of maximum reaction...
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