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Azospirillum brasilense glutamate synthase (GltS) is a complex iron–sulfur flavoprotein whose catalytically active αβ protomer (α subunit, 162kDa; β subunit, 52.3kDa) contains one FAD, one FMN, one [3Fe–4S] 0,+1 , and two [4Fe–4S] +1,+2 clusters. The structure of the α subunit has been determined providing information on the mechanism of ammonia transfer from l-glutamine to 2-oxoglutarate...
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