Unique aluminum nitride amorphous nanotubes filled with Ni nanoparticles have been successfully synthesized through the reaction of NH 3 over Ni–Al thin film at 1000°C, which is similar to the extended vapor–liquid–solid technique. The X-ray diffraction and high-resolution transmission electron microscopic results are in good agreement with the amorphous nature of AlN nanotubes and crystallinity of Ni nanoparticles. The AlN nanotubes were having average diameter 35nm and length ∼4μm, whereas the Ni nanoparticles were having 5nm in diameter. The unique structure showed excellent field emission property and high electrical conductivity ∼0.43kmho/m at room temperature. The mechanism of good field emission property has been explained in detail.