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P450 enzyme models carrying a SO 3− ligand coordinating to iron have been synthesized and characterized. These complexes show characteristics very similar to those of iron–heme cofactors of P450 enzymes. Their reactivity towards different reactions catalyzed by P450 enzymes such as epoxidation of double bonds, hydroxylation of non-activated C–H bonds, N-dealkylation of amines, and cleavage...
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